Modes of the Schrodinger Equation for the 1D Mexican Hat Potential

Introduction

            This documents the quantum mechanical results for the Mexican Hat Potential.  The parent page shows the positions, velocities, and the position occupation times of the potential.

Math

            The Schrodinger equation

( 2 2m d 2 d x 2 +V(x) )ψ=λψ MathType@MTEF@5@5@+= feaahiart1ev3aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr 4rNCHbGeaGqiVCI8FfYJH8YrFfeuY=Hhbbf9v8qqaqFr0xc9pk0xbb a9q8WqFfeaY=biLkVcLq=JHqpepeea0=as0Fb9pgeaYRXxe9vr0=vr 0=vqpWqaaeaabiGaciaacaqabeaadaqaaqaaaOqaamaabmaabaGaey OeI0YaaSaaaeaacqWIpecAdaahaaWcbeqaaiaaikdaaaaakeaacaaI YaGaamyBaaaadaWcaaqaaiaadsgadaahaaWcbeqaaiaaikdaaaaake aacaWGKbGaamiEamaaCaaaleqabaGaaGOmaaaaaaGccqGHRaWkcaWG wbGaaiikaiaadIhacaGGPaaacaGLOaGaayzkaaGaeqiYdKNaeyypa0 Jaeq4UdWMaeqiYdKhaaa@4B64@  

(1.1)

can be solved with reasonable accuracy using a finite difference matrix of the form shown below.

( 2 2 2mΔ x 2 +V( x 0 ) 2 2mΔ x 2 0 2 2mΔ x 2 2 2 2mΔ x 2 +V( x 0 +Δx) 2 2mΔ x 2 0 2 2mΔ x 2 2 2 2mΔ x 2 +V( x 0 +Δx) )( ψ 0 ψ 1 ψ 2 )=λ( ψ 0 ψ 1 ψ 2 ) MathType@MTEF@5@5@+= feaahiart1ev3aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr 4rNCHbGeaGqiVCI8FfYJH8YrFfeuY=Hhbbf9v8qqaqFr0xc9pk0xbb a9q8WqFfeaY=biLkVcLq=JHqpepeea0=as0Fb9pgeaYRXxe9vr0=vr 0=vqpWqaaeaabiGaciaacaqabeaadaqaaqaaaOqaamaabmaabaqbae qabmWaaaqaaiaaikdadaWcaaqaaiabl+qiOnaaCaaaleqabaGaaGOm aaaaaOqaaiaaikdacaWGTbGaeuiLdqKaamiEamaaCaaaleqabaGaaG OmaaaaaaGccqGHRaWkcaWGwbGaaiikaiaadIhadaWgaaWcbaGaaGim aaqabaGccaGGPaaabaGaeyOeI0YaaSaaaeaacqWIpecAdaahaaWcbe qaaiaaikdaaaaakeaacaaIYaGaamyBaiabfs5aejaadIhadaahaaWc beqaaiaaikdaaaaaaaGcbaGaaGimaaqaaiabgkHiTmaalaaabaGaeS 4dHG2aaWbaaSqabeaacaaIYaaaaaGcbaGaaGOmaiaad2gacqqHuoar caWG4bWaaWbaaSqabeaacaaIYaaaaaaaaOqaaiaaikdadaWcaaqaai abl+qiOnaaCaaaleqabaGaaGOmaaaaaOqaaiaaikdacaWGTbGaeuiL dqKaamiEamaaCaaaleqabaGaaGOmaaaaaaGccqGHRaWkcaWGwbGaai ikaiaadIhadaWgaaWcbaGaaGimaaqabaGccqGHRaWkcqqHuoarcaWG 4bGaaiykaaqaaiabgkHiTmaalaaabaGaeS4dHG2aaWbaaSqabeaaca aIYaaaaaGcbaGaaGOmaiaad2gacqqHuoarcaWG4bWaaWbaaSqabeaa caaIYaaaaaaaaOqaaiaaicdaaeaacqGHsisldaWcaaqaaiabl+qiOn aaCaaaleqabaGaaGOmaaaaaOqaaiaaikdacaWGTbGaeuiLdqKaamiE amaaCaaaleqabaGaaGOmaaaaaaaakeaacaaIYaWaaSaaaeaacqWIpe cAdaahaaWcbeqaaiaaikdaaaaakeaacaaIYaGaamyBaiabfs5aejaa dIhadaahaaWcbeqaaiaaikdaaaaaaOGaey4kaSIaamOvaiaacIcaca WG4bWaaSbaaSqaaiaaicdaaeqaaOGaey4kaSIaeuiLdqKaamiEaiaa cMcaaaaacaGLOaGaayzkaaWaaeWaaeaafaqabeWabaaabaGaeqiYdK 3aaSbaaSqaaiaaicdaaeqaaaGcbaGaeqiYdK3aaSbaaSqaaiaaigda aeqaaaGcbaGaeqiYdK3aaSbaaSqaaiaaikdaaeqaaaaaaOGaayjkai aawMcaaiabg2da9iabeU7aSnaabmaabaqbaeqabmqaaaqaaiabeI8a 5naaBaaaleaacaaIWaaabeaaaOqaaiabeI8a5naaBaaaleaacaaIXa aabeaaaOqaaiabeI8a5naaBaaaleaacaaIYaaabeaaaaaakiaawIca caGLPaaaaaa@9D29@      (1.2)

Figure 1: Schrodinger Equation in Finite Difference form with just three elements.

 The potential used for the plots below is shown in Figure 2.

Figure 2: Mexican Hat Potential used for the modes computed below.

 

The constant values used were for simplicity =1 MathType@MTEF@5@5@+= feaahiart1ev3aqatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr 4rNCHbGeaGqiVCI8FfYJH8YrFfeuY=Hhbbf9v8qqaqFr0xc9pk0xbb a9q8WqFfeaY=biLkVcLq=JHqpepeea0=as0Fb9pgeaYRXxe9vr0=vr 0=vqpWqaaeaabiGaciaacaqabeaadaqaaqaaaOqaaiabl+qiOjabg2 da9iaaigdaaaa@38D1@  and m=1 MathType@MTEF@5@5@+= feaahiart1ev3aqatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr 4rNCHbGeaGqiVCI8FfYJH8YrFfeuY=Hhbbf9v8qqaqFr0xc9pk0xbb a9q8WqFfeaY=biLkVcLq=JHqpepeea0=as0Fb9pgeaYRXxe9vr0=vr 0=vqpWqaaeaabiGaciaacaqabeaadaqaaqaaaOqaaiaad2gacqGH9a qpcaaIXaaaaa@389A@  .

Results

Figure 3 shows the lowest three modes while Figure 4 shows the next lowest three modes.  The fact that the wave function amplitude is very small near the center peak of the potential is probably due to tunneling of the particle through the peak.

 

Figure 3: Lowest three modes of Mexican Hat Potential along with their energy eigenvalues listed in the legend.

 

  ,

Figure 4: Next lowest three modes of  Mexican Hat Potential along with their energy eigenvalues listed in the legend.